Descriptive Statistics of Selected Heavy Metal in Dust Particles from Three Sampling Sites Within Ibadan Metropolis, Southwestern Nigeria
DOI:
https://doi.org/10.54536/ajec.v5i3.7879Keywords:
Ibadan Metropolis, Mechanic Workshops, Motor Parks, Roundabouts / Highways, Street DustsAbstract
This study investigates the concentration and distribution of heavy metals in dust particles from three sampling sites within Ibadan Metropolis. A total of 20 dust samples were collected from three distinct areas: Mechanic workshops (MWK), Motor parks (MPK), and Roundabouts/highways (RHW). The samples were prepared and processed at the geochemistry laboratory of the Polytechnic Ibadan. The process samples were analysed using Induced Couple Plasma- Atomic Emission Spectrometry (ICP-AES) at PAM BEE Analytical Laboratory Ibadan. The heavy metals analyzed include Cr, Zn, Fe, Pb, Cu, and Ni. The results indicated a wide range of heavy metal concentrations across the sampled locations. Cr ranged from 8.67 - 60.52mg/kg with a mean of 23.56 mg/kg, Zn from 64.15 - 534.22 mg/kg with a mean of 244.28 mg/kg, Fe from 319.62 - 3945.51 mg/kg with a mean of 3766.6 mg/kg, Pb from 13.715 - 368.19 mg/kg with a mean of 67.13 mg/kg, Cu from 13.72 - 61. Mg/kg with a mean of 30.79 mg/kg, and Ni fro20.81-33.18 mg/kg with a mean of 19.03 mg/kg. The results demonstrated that Pb was the dominant contaminant, reaching levels of considerable contamination (CF ≈ 3.35; Igeo ≈ 1.3), followed by moderate enrichment of Zn and Cr. Ni, Cu, and Fe remained within the low contamination range, suggesting primarily natural inputs with minimal anthropogenic influence. The overall PLI value (<1) indicates that, on average, the study area is not heavily polluted. However, localized hotspots, particularly around mechanic workshops and motor parks, present elevated risks. The contamination pattern followed the order: Pb > Zn > Cr > Ni > Cu > Fe, with Pb clearly emerging as the most concerning pollutant due to its toxicity and persistence. The findings underscore the need for continuous monitoring of heavy metals in urban dust, particularly Pb, which remains a significant environmental hazard. Although the overall pollution load index suggests acceptable site quality, the considerable contamination of Pb points to localized anthropogenic sources that should be addressed through stricter environmental management and control measures.
Downloads
References
Abbasi, S., Turner, A., & Kelly, F. J. (2017). Tackling the plastics problem: Heavy metal content of household, commercial and industrial plastic products sold on the UK market. Environmental Pollution, 231(1), 807–814. https://doi.org/10.1016/j.envpol.2017.08.024.
Adamiec, E., Jarosz-Krzemińska, E., & Wieszała, R. (2016). Heavy metals from non-exhaust vehicle emissions in urban and motorway road dusts. Environmental Monitoring and Assessment, 188(6), 369. https://doi.org/10.1007/s10661-016-5377-1
Adelekan, B. A. (2016). Determination of some heavy metals in roadside dust in Ibadan, Nigeria. Journal of Applied Sciences and Environmental Management, 20(4), 1047–1055. https://doi.org/10.4314/jasem.v20i4.26.
Addo, M. A., Darko, E. O., Gordon, C., Nyarko, B. J. B., & Gbadago, J. K. (2012). Heavy metal concentrations in road deposited dust at Ketu-south district, Ghana. International Journal of Science and Technology, 2(1), 28–39.
Al-Khashman, O. A. (2004). Heavy metal distribution in dust, street dust and soils from the work place in Karak Industrial Estate, Jordan. Atmospheric Environment, 38(39), 6803–6812. https://doi.org/10.1016/j.atmosenv.2004.09.011.
Amanambu, A. C. (2015). Health risk assessment of heavy metals in street dust of an urban environment in Nigeria. Environmental Monitoring and Assessment, 187(1), 4171. https://doi.org/10.1007/s10661-014-4171-y.
Ashrafi, S. D., Kamani, H., & Jaafari, J. (2014). Heavy metals contamination and distribution in street dusts of Tehran. Environmental Earth Sciences, 72(9), 3293–3303. https://doi.org/10.1007/s12665-014-3224-0.
Basart, S., Pérez, C., Cuevas, E., Baldasano, J. M., & Gobbi, G. P. (2016). Aerosol characterization in Northern Africa, Northeastern Atlantic, Mediterranean Basin and Middle East from direct-sun AERONET observations. Atmospheric Chemistry and Physics, 9(21), 8265–8282. https://doi.org/10.5194/acp-9-8265-2009.
Burgos, A., Moreno, T., Querol, X., de la Rosa, J. D., & Gibbons, W. (2008). Airborne trace element pollution in an industrialised city: Human health risks. Journal of Environmental Monitoring, 10(10), 1226–1236. https://doi.org/10.1039/B808815M.
Calderón, J., Navarrete, B., & Jiménez, J. (2001). Exposure to heavy metals in street dust: A biomonitoring approach. Science of the Total Environment, 281(1–3), 79–87. https://doi.org/10.1016/S0048-9697(01)00818-4.
Carrizales, L., Razo, I., Téllez-Hernández, J. I., Torres-Nerio, R., Torres, A., Batres, L. E., Cubillas, A. C., & Díaz-Barriga, F. (2006). Exposure to arsenic and lead of children living near a copper-smelter in San Luis Potosí, Mexico: Importance of soil contamination for exposure of children. Environmental Research, 101(1), 1–10. https://doi.org/10.1016/j.envres.2005.07.010
Charlesworth, S., De Miguel, E., & Ordóñez, A. (2011). A review of the distribution of particulate trace elements in urban terrestrial environments and its application to considerations of risk. Environmental Geochemistry and Health, 33(2), 103–123. https://doi.org/10.1007/s10653-010-9325-7
Chen, H., Lu, X., Li, L. Y., Gao, T., & Chang, Y. (2014). Metal contamination in campus dust of Xi’an, China: A study based on multivariate statistics and spatial distribution. Science of the Total Environment, 484, 27–35. https://doi.org/10.1016/j.scitotenv.2014.03.026
Christoforidis, A., & Stamatis, N. (2009). Heavy metal contamination in street dust and roadside soil along the major national road in Kavala’s region, Greece. Geoderma, 151(3–4), 257–263. https://doi.org/10.1016/j.geoderma.2009.04.016.
Councell, T. B., Duckenfield, K. U., Landa, E. R., & Callender, E. (2004). Tire-wear particles as a source of zinc to the environment. Environmental Science & Technology, 38(15), 4206–4214. https://doi.org/10.1021/es034631f
Dada, S. S. (2006). Proterozoic evolution of Nigeria. In O. A. Oshin (Ed.), Geology and Mineral Resources of Nigeria (pp. 29–44). NAPE Bulletin.
Ebrahimi, A., Kalantari, N., & Abbaspour, M. (2020). Human health risk assessment of heavy metals in urban dust of Tehran, Iran. Environmental Science and Pollution Research, 27(24), 29944–29956. https://doi.org/10.1007/s11356-020-09453-8.
Gope, M., Saha, N., & Sanyal, S. (2017). Characterization and health risk assessment of heavy metals in street dust of Asansol, India. Environmental Earth Sciences, 76(12), 419. https://doi.org/10.1007/s12665-017-6767-3.
Hemati, M., & Rahimi, E. (2020). Chronic exposure to heavy metals in street dust: Potential health risks for children and adults. Ecotoxicology and Environmental Safety, 195, 110496. https://doi.org/10.1016/j.ecoenv.2020.110496.
Hjortenkrans, D. S. T., Bergbäck, B. G., & Häggerud, A. V. (2006). New metal emission patterns in road traffic environments. Environmental Monitoring and Assessment, 117(1–3), 85–98. https://doi.org/10.1007/s10661-006-7706-2
Imperato, M., Adamo, P., Naimo, D., Arienzo, M., Stanzione, D., & Violante, P. (2003). Spatial distribution of heavy metals in urban soils of Naples city (Italy). Environmental Pollution, 124(2), 247–256. https://doi.org/10.1016/S0269-7491(02)00478-5
Khademi, H., Gabarrón, M., Abbaspour, A., Martínez-Martínez, S., Faz, A., & Acosta, J. A. (2019). Environmental impact assessment of heavy metals in street dust and road-deposited sediment: A review. Environmental Geochemistry and Health, 41(2), 939–956. https://doi.org/10.1007/s10653-018-0193-5.
Kowalska, J. B., Mazurek, R., Gąsiorek, M., & Zaleski, T. (2018). Pollution indices as useful tools for the comprehensive evaluation of the degree of soil contamination — A review. Environmental Geochemistry and Health, 40(6), 2395–2420. https://doi.org/10.1007/s10653-018-0106-z
Laidlaw, M. A. S., & Filippelli, G. M. (2008). Resuspension of urban soils as a persistent point source of lead poisoning in children. Applied Geochemistry, 23(8), 2344–2356. https://doi.org/10.1016/j.apgeochem.2008.05.009
Lu, X., Wang, L., Li, L. Y., Lei, K., Huang, L., & Kang, D. (2010). Multivariate statistical analysis of heavy metals in street dust of Baoji, NW China. Journal of Hazardous Materials, 173(1–3), 744–749. https://doi.org/10.1016/j.jhazmat.2009.09.001
Men, C., Liu, R., Xu, F., Wang, Q., Guo, L., & Shen, Z. (2018). Pollution characteristics, risk assessment, and source apportionment of heavy metals in road dust in Beijing, China. Science of the Total Environment, 612, 138–147. https://doi.org/10.1016/j.scitotenv.2017.08.123
Nwachukwu, M. A., Feng, H., & Achilike, K. (2010). Integrated studies for automobile wastes and vehicular pollution management in developing countries. Environmental Geochemistry and Health, 32(3), 191–214. https://doi.org/10.1007/s10653-009-9267-2
Pant, P., & Harrison, R. M. (2013). Estimation of the contribution of road traffic emissions to particulate matter concentrations from field measurements: A review. Atmospheric Environment, 77, 78–97. https://doi.org/10.1016/j.atmosenv.2013.04.028
Querol, X., Alastuey, A., Moreno, T., Viana, M. M., Castillo, S., Pey, J., ... & Artiñano, B. (2008). Spatial and temporal variations in airborne particulate matter (PM10 and PM2.5) across Spain 1999–2005. Atmospheric Environment, 42(17), 3964–3979. https://doi.org/10.1016/j.atmosenv.2006.10.071
Rasmussen, P. E., Beauchemin, S., Chenier, M., Levesque, C., MacLean, L. C. W., Marro, L., ... & Gardner, H. D. (2011). Canadian house dust study: Population-based concentrations, loads and loadings of arsenic, cadmium, chromium, copper, nickel, lead, and zinc inside urban homes. Science of the Total Environment, 409(22), 4885–4897. https://doi.org/10.1016/j.scitotenv.2011.07.033
Tang, R., Ma, K., Zhang, Y., & Mao, Q. (2017). The spatial characteristics and health risk assessment of heavy metals in street dust of urban areas in China. Science of the Total Environment, 580, 1363–1374. https://doi.org/10.1016/j.scitotenv.2016.12.096.
Thorpe, A., & Harrison, R. M. (2008). Sources and properties of non-exhaust particulate matter from road traffic: A review. Science of the Total Environment, 400(1–3), 270–282. https://doi.org/10.1016/j.scitotenv.2008.06.007
Turekian, K. K., & Wedepohl, K. H. (1961). Distribution of the elements in some major units of the Earth’s crust. Geological Society of America Bulletin, 72(2), 175–192. https://doi.org/10.1130/0016-7606(1961)72[175:DOTEIS]2.0.CO;2.
Werkenthin, M., Kluge, B., & Wessolek, G. (2014). Metals in European roadside soils and soil solution — A review. Environmental Pollution, 189, 98–110. https://doi.org/10.1016/j.envpol.2014.02.025
Yıldırım, D., & Tokalıoğlu, Ş. (2016). Source apportionment of heavy metals in street dusts of Kayseri, Turkey. Atmospheric Pollution Research, 7(2), 309–319. https://doi.org/10.1016/j.apr.2015.10.012.
Zhang, C., Qiao, Q., Appel, E., & Huang, B. (2012). Discriminating sources of anthropogenic heavy metals in urban street dusts using magnetic and chemical methods. Journal of Geochemical Exploration, 119–120, 60–75. https://doi.org/10.1016/j.gexplo.2012.06.014.
Zheng, N., Liu, J., Wang, Q., & Liang, Z. (2010). Health risk assessment of heavy metal exposure to street dust in the zinc smelting district, northeast of China. Science of the Total Environment, 408(4), 726–733. https://doi.org/10.1016/j.scitotenv.2009.10.075
Downloads
Published
Issue
Section
License
Copyright (c) 2026 Apanpa Kazeem Abidemi, Oladimeji Razaq Gboyega, Adeogbo Ayoade Olusola

This work is licensed under a Creative Commons Attribution 4.0 International License.




