Influence of Twin-Screw Extrusion on The Dispersion of Nanoclay in Vinylester Composites
DOI:
https://doi.org/10.54536/ajaset.v5i2.101Keywords:
 Twin-Screw Extrusion,  Nanoclay,,  Dispersion,,  SEM,,  XRDAbstract
This paper reports the dispersion of nanoclay in vinylester using co-rotating twin screw extrusion and ultrasonication for preparing nanoclay/vinylester gel coat. Two sets MMT/vinylester specimens, namely Type 1 and Type 2 were prepared for comparative studies. While Type 1 specimens were prepared using ultrasonication only, Type 2 specimens were prepared using both ultrasonication and twin-screw extrusion. Type 2 specimens showed lower levels of nanoclay intercalation and higher levels of exfoliation. By using the MMT/vinylester gel coat so prepared by the two different routes, MMT/vinylester/glass specimens were fabricated and tested for mechanical properties. Type 2 based nanocomposite specimens showed greater values of ultimate tensile strength, flexural strength, interlaminar shear strength and impact strength. Scanning Electron Micrographs (SEM) of tensile fractured Type 2 based specimens showed less agglomeration of nanoclay than that of Type 1 based specimens.
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Hotta S, Paul D R. (2016) Nanocomposites formed from linear lowdensity polyethylene and organoclays. Polymer, 45:7639-7654.
Jo B, Park S, Kim D. (2017) “Mechanical properties of nano-MMT reinforced polymer composite and polymer concreteâ€, Construct. Building Mater, 22, pp.14-20
Park J H, Jana S. (2018) “Mechanism of exfoliation of nanoclay particles in epoxy- clay nanocompoistesâ€. Macromolecules, 36, pp. 2758-2768
Ray S S, Okamoto M. (2016) “Polymer/layered Silicate Nanocomposite: A Review from Preparation to Processingâ€, Prog. Polymer Sci, 28, pp.1539-1641
Schmidt D, Shah D, Giannelis E P. (2019) “Advances in Polymer/Layered Silicate Nanocompositesâ€, Current Opinion in Solid State and Materials Science, 6, pp. 205-212
Seng Chai See, Zhong Yi Zhang, Hom Nath Dhakal, Richardson MOW. (2016) “Nanomechanical behavior and thermal degradation of nanoclays and enhanced marine gelcoat systemâ€. Mat, Engg, Innova, 1, pp.21-39
Subramaniyan A K, Sun C T. (2019) “Toughening Polymeric Composites Using Nanoclay: Crack tip Scale Effects on Fracture Toughnessâ€, Composites Part A, 38, pp. 34-43
Tae Yong Hwang, Hee Jung Kim, Youngjoon Ahn and Jae Wook Lee. (2018)“Influence of twin-screw extrusion processing condition on the properties of PP/MWCNT nanocompoistes†Korea-Australia Rheology Journal, 22(2), 141-148.
Tjong S.C.(2018), “Structural and Mechanical Properties of Polymer Nanocomposites. Materials Science and Engineeringâ€, 53, pp. 73-197.
Wang L, Wang K, Chen L, Zhang Y, He C. (2016), “Preparation, Morphology and Thermal/Mechanical Properties of Epoxy/Nanoclay Composite. Compositesâ€, Part A: Applied Science and Manufacturing, 37, pp.1890-1896
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Copyright (c) 2021 Bommanna K, Radha H R, Yuvaraja Naik, Mahendra K V, A Hareesh
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